Fractional Distillation and Crude Oil

Fractional distillation is a process that separates the components in a mixture based on their different boiling points.

Crude oil is a complex mixture of hydrocarbons that is extracted from the ground. However, crude oil itself is not a useful substance, as its properties and composition vary widely. To make crude oil useful, it must be broken down into simpler mixtures. These mixtures are called fractions, which contain hydrocarbons with similar carbon chain lengths and properties.

We can separate the various hydrocarbons in crude oil as they all have different boiling points. By breaking down crude oil into these different fractions, we can isolate the specific hydrocarbons we need for various purposes. This allows us to make use of the different properties of each fraction to create a wide range of useful products.

Process of Fractional Distillation with Crude oil

Let’s look at how the process of fractional distillation works with crude oil:

1. Heated crude oil enters the fractionating column at the bottom, and the vapours rise up through the column.

  • The column is hotter at the bottom and cooler towards the top

2. As the vapours rise, hydrocarbons with higher boiling points start to condense into liquids at lower temperatures, towards the bottom of the column.

3. Hydrocarbons with lower boiling points continue to rise further up the column.

4. As the different hydrocarbons reach different heights in the column, they condense into liquids at different temperatures, forming separate fractions. Once the hydrocarbons condense into liquid, they are led out of the column.

The separation of the hydrocarbons in crude oil occurs because different hydrocarbons have different boiling points.

Longer chain hydrocarbons have stronger intermolecular forces, so they have higher boiling points. These hydrocarbons require more energy to break the forces of attraction between their molecules. As a result, they evaporate and condense in the fractions near the bottom of the fractionating column.

Shorter chain hydrocarbons have weaker intermolecular forces, so they have lower boiling points. This means that they will stay as a gas for much longer and rise further up the column. Less energy is required to break the forces of attraction between their molecules. As a result, they condense in the fractions near the top of the column.


Petrochemicals are substances that we get from crude oil. These substances are used as feedstocks, which means raw materials. The petrochemical industry then transforms these feedstocks into a wide range of products with various uses, including:

  • Solvents
  • Lubricants
  • Detergents
  • Polymers

Crude oil is also useful as fuel. Different fractions of crude oil have different properties and can be used for various purposes. Here’s a table showing the different fractions of crude oil and their uses:

Liquified petroleum gasesDomestic cooking and heating
PetrolFuel for cars
KeroseneFuel for aircrafts
Diesel oilFuels for some vehicles
Heavy fuel oilFuel for ships and power stations
BitumenSurface roads and roofs