Separating Product and Recycling Unreacted Reactants Flashcards

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In an industrial chemical process, what does "separating the product" mean?

It means taking the wanted chemical out of the reaction mixture so it is on its own.

Why is separation needed after a reversible reaction reaches equilibrium?

At equilibrium the mixture has both reactants and products, so we must separate the product to collect it and allow more reactants to be reused.

In the Haber process, how is ammonia separated from the nitrogen and hydrogen after the reactor?

The gas mixture is cooled so that ammonia condenses to a liquid, which is then removed.

Why does ammonia condense when the Haber mixture is cooled but nitrogen and hydrogen stay as gases?

Ammonia has a higher boiling point than nitrogen and hydrogen, so it turns to liquid first when cooled.

What happens to the unreacted nitrogen and hydrogen in the Haber process after ammonia is removed?

They are recycled and fed back into the reactor to react again.

Why do factories recycle unreacted reactants instead of throwing them away?

Recycling saves raw materials, cuts costs, reduces waste and increases the overall amount of product made.

What is meant by "yield per pass" in a process like the Haber process?

Yield per pass is the percentage of reactants that turn into product each time the mixture goes through the reactor once.

How does recycling unreacted reactants affect the overall yield of a reversible process?

Recycling makes the overall yield much higher, because reactants get many chances to react, not just one.

Why can a reversible reaction like the Haber process not reach 100% conversion in a single pass through the reactor?

Because the reaction reaches equilibrium, where forward and backward reactions are equal, so some reactants always remain.

What simple piece of equipment is used to separate ammonia from the gas mixture in the Haber process?

A cooling system with a condenser is used to cool the gases so ammonia liquefies and can be removed.

How does recycling unreacted reactants help the environment?

It reduces waste gases, uses fewer raw materials and can lower the energy used per tonne of product.